in a word, efficiency.
A flat, rectangular window is a window is a whole lot cheaper and easier to manufacture, design for, install, and replace than a curved amorphous one. During the modernist period, when architecture, furniture, and products where really first reduced to their most minimal, efficient selves, part of the thrust of the movement was to make better solutions available to more people. So while their was an aesthetic element to doing it well, the reason was to be efficient so more people could afford a better life.
Now, many of the objects we use are still rectangles, still for efficiency. Take your phone. Could it have a curved circular display? Sure. It would cost 10 times as much though, and chances are you aren’t going to pay 10 times as much for a phone. Not only would the display cost more, but the content it views would have to be totally reshuffled. Most of the content is also based on rectangles, which was all based on the rectangular pages of printed books, which were rectangles because… you guessed it, it was efficient to manufacture, print, process, bind, and ship rectangular paper… so, your screen id going to be a rectangle, which is good because the PC board it sits above is also a rectangle for the same reason of efficiency… could your phone be a curved circle with a flat rectangular display? Yes, it would just be huge, and thus, inefficient to use, so you wouldn’t want it.
So we have this rectilinear manufactured world. Could the bench you are sitting on be a blob? Yes, it would not be horribly inefficient, and there are lots of examples of organic furniture. It has to respond to the body , which is organic… but it also is caught up responding to the efficient architecture, and the efficient products, which are all rectangles. Also, furniture tends to be designed by architects or designers who frequent rectilinear forms, and prefer order and reason (typically). I think for these reasons, the majority of furniture is pretty rectilinear. But anything that responds to the body has more opportunity to be organic, furniture, hand tools, footwear…