Outdoor enclosures are usually plated and painted. Either one by itself doesn’t offer sufficient protection from the elements. Some paint companies claim durable coatings, but these are often special purpose and expensive. Plating and painting are commodity processes and somewhat inexpensive.
All plating processes are environmental disasters. Get used to it. It’s why plating companies ensure they have beautiful flower beds and green lawns outside their plant, behind doors it’s acrid, steaming, evil brown vats with odd wire parts cages above.
Plastics don’t weather well the abuses of long term environmental exposure regardless of climate. Ultraviolet light is murder to polymers, as is repeated thermal cycling. Also, assuming your outdoor enclosure with a PCB is for some type of electronic communication, EMC will be an issue as there is no way to ensure long term shielding of outdoor installed plastics enclosures, except for metal foils or internal chassis.
In terms of sealing, by design there are never up facing openings, other vents, seams or windows require screens and / or multiple turns blocking direct spray access. There are numerous types of gaskets available.
Ingress Protection describes levels of water and dust susceptibility. NEMA and assorted telco standards have design guides.
Walk around and look at cable repeater boxes, telephone switch boxes, highway signage, etc. You’ll start to recognize intent.